​Combining the benefits of heterodyne detection (ideally offering shot noise limited detection together with high spectral resolution spectrometry) and the spectral processor, we have demonstrated a relatively simple, compact, and eye-safe system that achieves high detection sensitivity (< 1ppm.m/√Hz for the strongly absorbing molecules) and quantitative chemical selectivity.

An eye-safe, mid-IR hyperspectral active standoff detection system provides identification, detection, and confident quantification of chemical mixtures. Standoff chemical detection is the ability to detect chemicals in an object that is some distance from the measurement instrument. This capability, along with chemical identification and quantification, is highly sought after in security and defence applications. Active optical techniques, such as laser induced breakdown spectroscopy, Raman spectroscopy, laser induced fluorescence, or differential absorption lidar, do not always meet the eye-safety requirements, or cannot deliver both high sensitivity and high selectivity. For these reasons, RAL Space have investigated a solution that exploits recent progress in widely tunable mid-IR laser sources combined with the benefits of laser heterodyne detection. Heterodyne detection involves the mixing of the light to analyse spectrally with that of a reference laser (the local oscillator) to operate frequency down-conversion. It allows spectrometry with an ultra-high resolution, and a high sensitivity by overcoming the detector noise.

The mid-IR region of the electromagnetic spectrum (2–20 µm) is of particular interest for remote molecular detection since the atmosphere is transparent in the medium-wave IR (MWIR 3- 5 µm) and the long-wave IR (LWIR 8–12 µm), which allows for long-range sensing. In the mid-IR region, molecules exhibit intense fundamental rotational-vibrational bands that create large molecular absorption cross-sections, which enable enhanced detection sensitivity. Furthermore, the uniqueness of the spectral signatures, if properly resolved, provides information about functional groups and molecular fingerprints, which relates to chemical selectivity. To exploit these benefits, the Spectroscopy Group developed the Active Coherent Laser Spectrometer (ACLaS), which can also be described as a mid-IR hyperspectral heterodyne lidar. We combined this approach with the development of spectral processing algorithms that are able to deconvolve the information contained in complex multi-chemical mixtures. Our first ACLaS demonstrators used continuously tunable quantum cascade lasers (QCLs) to provide both the active illumination source and the local oscillator field (slightly shifted in frequency) of the laser heterodyne detection scheme. Using optical heterodyne detection enables sensitive detection of the returned backscattered field, and ultra-high spectral resolution at the receiver, which is typically matched to the illuminating laser linewidth (~ few MHz) and efficiently suppresses any background radiation. By continuously tuning the local oscillator/ illuminator frequency, we can obtain very high spectral resolution signatures of chemical absorption along the line of sight. We tested two systems over standoff ranges covering 1–40m, using topographic targets such as brick, cardboard, painted metal, and aluminum foil. The first system was based on distributed feedback QCLs tunable over ~5–10 cm-1, and was well suited to study light molecules exhibiting narrow-band absorption features. A second system using an external cavity QCL (continuously tunable over ~80 cm-1/ demonstrated standoff detection of complex mixtures of vapors, including light and heavy molecules, which produced composite spectral signatures that mixed broadband and narrow-band structures.

High-resolution spectra are of no use to the end-user without their robust conversion into quantitative metrics. To that end, we developed a spectral processor based on the optimum estimation method. This approach relied on a forward model that describes the full physics known about the detection scenario and the instrument and its inversion, enabling us to recover molecular concentration parameters from spectral data. If necessary, we could add a priori parameters—and the level of confidence we had in them—to constrain the inversion further. This approach not only carries out the spectral inversion, it also provides a series of diagnostic tools to estimate error and bias propagation. This allows us to quantify the level of cross-talk between retrieved parameters, and as a result, provides a metric to estimate the level of confidence in the final output.

We successfully tested the system (ACLaS and spectral processor) on nine different vapor phase molecules, and performed a very preliminary demonstration on surface deposits. The widely tunable mid-IR laser sources enabled good chemical versatility. The range of chemicals studied spans atmospheric species (water, carbon dioxide, nitrous oxide and methane), industrial gases (including the main components of natural gas) and explosives (ethylene glycol dinitrate and the precursor hydrogen peroxide). Combined with our processing algorithm, concentrations down to part per billion levels can be confidently measured even in spectrally cluttered environments.

For more information please contact: RAL Space Enquiries​​